Guys, in this discussion you need to account for the whole of internal ballistics, not just parts of it. I will point out that it matters quite a bit whether OAL you compare to each other is with bullet touching the rifling lands or not. The case that holds the bullet can not ever make pressure rise to anywhere near the max pressure, simply because the bullet will depart. Next stop is engaging the rifling. Two things can happen there - if the pressure had grown high and fast enough to sustain the driving force, the bullet goes into rifling. If the pressure drops due to sudden bullet move and corresponding volume increase to the point that the bullet stops at the rifling, the pressure curve would probably have dent before starting to grow again. Also, if the bullet moves just too little to gain momentum enough to overcome the rifling resistence, it just compares to the scenario where bullet already touched the rifling from the beginning, or largish OAL. The hardest is the event of engaging the rifling, because the bullet must deform. But overall, the pressure peak is determined purely by the moment of inertia of the bullet weight - thats the main "reaction" part that defines the working pressure. Powder is selected so that for the duration of bullet accelerating in the barrel, the gases expand at a higher rate than the bullet is making room for them, until the powder is burnt and the pressure starts to drop. That is the reason why you must use less fast powder with heavier bullets to stay within safety margins, and need slower burning powder to accelerate heavy bullet upto speed. Consider a bullet jammed in the middle of the barrel due to lack of powder load. What happens when you fire next round into this barrel? Its not that this stuck bullet is jammed there hard, its that the moment the next bullet reaches it, the sum of their masses is creating much higher "reaction" to the expanding gasses, not moving out of the way fast enough and thus gas pressure goes over safe limits. What this means wrt OAL discussion? OAL does very little in overpressure department. If you press the same bullet deeper, it does not change the peak pressure much at all, because as soon as presure builds the bullet jumps into rifling and makes space as large as round with larger OAL has. Why you see higher muzzle velocity is more to do with the fact that when bullet has accelerated from the moment it overcame the case grip until the point of engaging rifling, it may have enough momentum to not ever stop there and continue accelerating, thus have effectively slightly longer time to get to higher speed. With longer OAL bullet sits longer at still until the gas pressure builds up to force it to deform and start moving. That infact may require higher gas pressure to happen, and depends on bullet diameter too. So, wrt max muzzle velocity, maximum OAL is not the best choice. You could start with longest OAL with some fixed safe charge, and work OAL down from there until there is no more notable increase in muzzle velocity. Thats probably the opimal OAL for that bullet and that charge combo. Then work up your charge to required PF. There are other reasons why max OAL may be chosen despite the added difficulty to reach higher muzzle speeds, mostly to do with how the bullet engages with the rifling and eventual accuracy.